Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

Huan Xiang; Ruojia Xin; Natthawan Prasongthum; Paweesuda Natewong; Tawan Sooknoi; Jiawei Wang; Prasert Reubroycharoen; Xiaolei Fan

doi:10.1016/j.recm.2021.12.002

Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

Huan Xiang, Ruojia Xin, Natthawan Prasongthum, Paweesuda Natewong, Tawan Sooknoi, Jiawei Wang, Prasert Reubroycharoen^*, Xiaolei Fan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

Original language	English
Pages (from-to)	47-68
Journal	Resources Chemicals and Materials
Volume	1
Issue number	1
Early online date	24 Jan 2022
DOIs	https://doi.org/10.1016/j.recm.2021.12.002
Publication status	Published - Mar 2022

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10.1016/j.recm.2021.12.002Licence: CC BY-NC-ND 3.0

Catalytic conversion of bioethanol to value-added chemicals and fuels
© 2021 The Authors. Published by Elsevier B.V. on behalf of Shenyang University of Chemical Technology. This is an open access article under the CC BY-NC-ND license
Final published version, 3.33 MBLicence: CC BY-NC-ND 3.0

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title = "Catalytic conversion of bioethanol to value-added chemicals and fuels: A review",

abstract = "Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.",

author = "Huan Xiang and Ruojia Xin and Natthawan Prasongthum and Paweesuda Natewong and Tawan Sooknoi and Jiawei Wang and Prasert Reubroycharoen and Xiaolei Fan",

note = "{\textcopyright} 2021 The Authors. Published by Elsevier B.V. on behalf of Shenyang University of Chemical Technology. This is an open access article under the CC BY-NC-ND license",

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doi = "10.1016/j.recm.2021.12.002",

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T1 - Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

AU - Xiang, Huan

AU - Xin, Ruojia

AU - Prasongthum, Natthawan

AU - Natewong, Paweesuda

AU - Sooknoi, Tawan

AU - Wang, Jiawei

AU - Reubroycharoen, Prasert

AU - Fan, Xiaolei

PY - 2022/3

Y1 - 2022/3

N2 - Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

AB - Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

UR - https://www.sciencedirect.com/science/article/pii/S2772443321000027?via%3Dihub

U2 - 10.1016/j.recm.2021.12.002

DO - 10.1016/j.recm.2021.12.002

M3 - Article

SN - 2772-4433

VL - 1

SP - 47

EP - 68

JO - Resources Chemicals and Materials

JF - Resources Chemicals and Materials

IS - 1

ER -

Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

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