Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements

Petra J. van Koningsbruggen; Joel S. Miller

doi:10.1016/j.solidstatesciences.2008.04.030

Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements

Petra J. van Koningsbruggen, Joel S. Miller

Chemical Engineering & Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Fe{HB(CHN)} is observed by variable temperature infrared and magnetic studies to have a spin transition between the low spin S = 0 and high spin S = 2 states at 331 K (58 °C) with thermal hysteresis of ~1.5 K. Changes in the triazole ligand IR absorptions demonstrate that distant non-metal-ligand vibrations are altered upon the change in electronic structure associated with the spin-crossover can be used to monitor the the spin-crossover transition.

Original language	English
Pages (from-to)	1804-1806
Number of pages	3
Journal	Solid state sciences
Volume	10
Issue number	12
Early online date	30 May 2008
DOIs	https://doi.org/10.1016/j.solidstatesciences.2008.04.030
Publication status	Published - Dec 2008

Keywords

spin-crossover

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10.1016/j.solidstatesciences.2008.04.030

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title = "Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements",

abstract = "Fe{HB(CHN)} is observed by variable temperature infrared and magnetic studies to have a spin transition between the low spin S = 0 and high spin S = 2 states at 331 K (58 °C) with thermal hysteresis of ~1.5 K. Changes in the triazole ligand IR absorptions demonstrate that distant non-metal-ligand vibrations are altered upon the change in electronic structure associated with the spin-crossover can be used to monitor the the spin-crossover transition.",

keywords = "spin-crossover",

author = "{van Koningsbruggen}, {Petra J.} and Miller, {Joel S.}",

year = "2008",

month = dec,

doi = "10.1016/j.solidstatesciences.2008.04.030",

language = "English",

volume = "10",

pages = "1804--1806",

journal = "Solid state sciences",

issn = "1293-2558",

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Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements. / van Koningsbruggen, Petra J.; Miller, Joel S.
In: Solid state sciences, Vol. 10, No. 12, 12.2008, p. 1804-1806.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements

AU - van Koningsbruggen, Petra J.

AU - Miller, Joel S.

PY - 2008/12

Y1 - 2008/12

N2 - Fe{HB(CHN)} is observed by variable temperature infrared and magnetic studies to have a spin transition between the low spin S = 0 and high spin S = 2 states at 331 K (58 °C) with thermal hysteresis of ~1.5 K. Changes in the triazole ligand IR absorptions demonstrate that distant non-metal-ligand vibrations are altered upon the change in electronic structure associated with the spin-crossover can be used to monitor the the spin-crossover transition.

AB - Fe{HB(CHN)} is observed by variable temperature infrared and magnetic studies to have a spin transition between the low spin S = 0 and high spin S = 2 states at 331 K (58 °C) with thermal hysteresis of ~1.5 K. Changes in the triazole ligand IR absorptions demonstrate that distant non-metal-ligand vibrations are altered upon the change in electronic structure associated with the spin-crossover can be used to monitor the the spin-crossover transition.

KW - spin-crossover

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U2 - 10.1016/j.solidstatesciences.2008.04.030

DO - 10.1016/j.solidstatesciences.2008.04.030

M3 - Article

AN - SCOPUS:56949098063

SN - 1293-2558

VL - 10

SP - 1804

EP - 1806

JO - Solid state sciences

JF - Solid state sciences

IS - 12

ER -

Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements

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