Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass

Fei Cheng; Stephen M. Kelly; Frédéric Lefebvre; Adam F. Lee; Karen Wilson; Stephen Clark; John S. Bradley

doi:10.1039/b504835d

Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass

Fei Cheng, Stephen M. Kelly, Frédéric Lefebvre, Adam F. Lee, Karen Wilson, Stephen Clark, John S. Bradley

Research output: Contribution to journal › Article › peer-review

Abstract

A high-surface-area silicon oximide-based gel [SiOC(H)=NSi]_m[Si₂N-C(H)=O]_n[SiN(H)-C(H)=O]_p[SiOC(H)=NH]_q[SiNH]_r[SiNH₂]_s[SiNMe₂]_t was prepared via a formamide-based aminolysis of tris(dimethylamino)silylamine, (Me₂N)₃SiNH₂. The structure of the gel and the mechanism of formation are elucidated. Pyrolysis of the gel at 1000 °C under N2 flow gave an amorphous microporous oxynitride-based glass with a BET surface area of 195 m2 g⁻¹.

Original language	English
Pages (from-to)	3039-3044
Number of pages	6
Journal	Journal of Materials Chemistry
Volume	15
Issue number	29
Early online date	15 Jun 2005
DOIs	https://doi.org/10.1039/b504835d
Publication status	Published - 7 Aug 2005

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title = "Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass",

abstract = "A high-surface-area silicon oximide-based gel [SiOC(H)=NSi]m[Si2N-C(H)=O]n[SiN(H)-C(H)=O]p[SiOC(H)=NH]q[SiNH]r[SiNH2]s[SiNMe2]t was prepared via a formamide-based aminolysis of tris(dimethylamino)silylamine, (Me2N)3SiNH2. The structure of the gel and the mechanism of formation are elucidated. Pyrolysis of the gel at 1000 °C under N2 flow gave an amorphous microporous oxynitride-based glass with a BET surface area of 195 m2 g−1.",

author = "Fei Cheng and Kelly, {Stephen M.} and Fr{\'e}d{\'e}ric Lefebvre and Lee, {Adam F.} and Karen Wilson and Stephen Clark and Bradley, {John S.}",

year = "2005",

month = aug,

day = "7",

doi = "10.1039/b504835d",

language = "English",

volume = "15",

pages = "3039--3044",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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}

Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass. / Cheng, Fei; Kelly, Stephen M.; Lefebvre, Frédéric et al.
In: Journal of Materials Chemistry, Vol. 15, No. 29, 07.08.2005, p. 3039-3044.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass

AU - Cheng, Fei

AU - Kelly, Stephen M.

AU - Lefebvre, Frédéric

AU - Lee, Adam F.

AU - Wilson, Karen

AU - Clark, Stephen

AU - Bradley, John S.

PY - 2005/8/7

Y1 - 2005/8/7

N2 - A high-surface-area silicon oximide-based gel [SiOC(H)=NSi]m[Si2N-C(H)=O]n[SiN(H)-C(H)=O]p[SiOC(H)=NH]q[SiNH]r[SiNH2]s[SiNMe2]t was prepared via a formamide-based aminolysis of tris(dimethylamino)silylamine, (Me2N)3SiNH2. The structure of the gel and the mechanism of formation are elucidated. Pyrolysis of the gel at 1000 °C under N2 flow gave an amorphous microporous oxynitride-based glass with a BET surface area of 195 m2 g−1.

AB - A high-surface-area silicon oximide-based gel [SiOC(H)=NSi]m[Si2N-C(H)=O]n[SiN(H)-C(H)=O]p[SiOC(H)=NH]q[SiNH]r[SiNH2]s[SiNMe2]t was prepared via a formamide-based aminolysis of tris(dimethylamino)silylamine, (Me2N)3SiNH2. The structure of the gel and the mechanism of formation are elucidated. Pyrolysis of the gel at 1000 °C under N2 flow gave an amorphous microporous oxynitride-based glass with a BET surface area of 195 m2 g−1.

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UR - http://pubs.rsc.org/en/Content/ArticleLanding/2005/JM/b504835d#!divAbstract

U2 - 10.1039/b504835d

DO - 10.1039/b504835d

M3 - Article

AN - SCOPUS:23644448587

SN - 0959-9428

VL - 15

SP - 3039

EP - 3044

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 29

ER -

Preparation of a microporous silicon oximide gel from the reaction of tris(dimethylamino)silylamine with formamide and its pyrolytic conversion into a silicon oxynitride based glass

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