Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

Frédérick Dorson; Yann Molard; Stéphane Cordier; Bruno Fabre; Olga Efremova; David Rondeau; Yuri Mironov; Viorel Cîrcu; Nikolay Naumov; Christiane Perrin

doi:10.1039/B822105G

Selective functionalisation of Re₆ cluster anionic units: from hexa-hydroxo [Re₆Q₈(OH)₆]⁴⁻ (Q = S, Se) to neutral trans-[Re₆Q₈L₄L′₂] hybrid building blocks

Frédérick Dorson, Yann Molard, Stéphane Cordier, Bruno Fabre, Olga Efremova, David Rondeau, Yuri Mironov, Viorel Cîrcu, Nikolay Naumov, Christiane Perrin

Chemical Engineering & Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [Re6Q8(OH)6]4- (Q = S, Se) with p-tertbutylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.

Original language	English
Pages (from-to)	1297-1299
Number of pages	3
Journal	Dalton Transactions
Volume	2009
Issue number	8
DOIs	https://doi.org/10.1039/B822105G
Publication status	Published - 28 Feb 2009

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10.1039/B822105G

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title = "Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks",

abstract = "The reaction of [Re6Q8(OH)6]4- (Q = S, Se) with p-tertbutylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.",

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doi = "10.1039/B822105G",

language = "English",

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journal = "Dalton Transactions",

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T1 - Selective functionalisation of Re6 cluster anionic units

T2 - from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

AU - Dorson, Frédérick

AU - Molard, Yann

AU - Cordier, Stéphane

AU - Fabre, Bruno

AU - Efremova, Olga

AU - Rondeau, David

AU - Mironov, Yuri

AU - Cîrcu, Viorel

AU - Naumov, Nikolay

AU - Perrin, Christiane

PY - 2009/2/28

Y1 - 2009/2/28

N2 - The reaction of [Re6Q8(OH)6]4- (Q = S, Se) with p-tertbutylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.

AB - The reaction of [Re6Q8(OH)6]4- (Q = S, Se) with p-tertbutylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.

U2 - 10.1039/B822105G

DO - 10.1039/B822105G

M3 - Article

SN - 1477-9226

VL - 2009

SP - 1297

EP - 1299

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

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Selective functionalisation of Re₆ cluster anionic units: from hexa-hydroxo [Re₆Q₈(OH)₆]⁴⁻ (Q = S, Se) to neutral trans-[Re₆Q₈L₄L′₂] hybrid building blocks