Synthesis and characterization of nanoporous phospho-tungstate organic-inorganic hybrid materials

Katabathini N. Rao; Lee D. Dingwall; Pratibha L. Gai; Adam F. Lee; Stewart J. Tavener; Nigel A. Young; Karen Wilson

doi:10.1039/b715826b

Synthesis and characterization of nanoporous phospho-tungstate organic-inorganic hybrid materials

Katabathini N. Rao, Lee D. Dingwall, Pratibha L. Gai, Adam F. Lee, Stewart J. Tavener, Nigel A. Young, Karen Wilson

Research output: Contribution to journal › Article › peer-review

Abstract

Nanoporous phospho-tungstate organic-inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N₂ adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

Original language	English
Pages (from-to)	868-874
Number of pages	7
Journal	Journal of Materials Chemistry
Volume	18
Issue number	8
Early online date	16 Jan 2008
DOIs	https://doi.org/10.1039/b715826b
Publication status	Published - 2008

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title = "Synthesis and characterization of nanoporous phospho-tungstate organic-inorganic hybrid materials",

abstract = "Nanoporous phospho-tungstate organic-inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.",

author = "Rao, {Katabathini N.} and Dingwall, {Lee D.} and Gai, {Pratibha L.} and Lee, {Adam F.} and Tavener, {Stewart J.} and Young, {Nigel A.} and Karen Wilson",

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AU - Rao, Katabathini N.

AU - Dingwall, Lee D.

AU - Gai, Pratibha L.

AU - Lee, Adam F.

AU - Tavener, Stewart J.

AU - Young, Nigel A.

AU - Wilson, Karen

PY - 2008

Y1 - 2008

N2 - Nanoporous phospho-tungstate organic-inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

AB - Nanoporous phospho-tungstate organic-inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

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UR - http://pubs.rsc.org/en/Content/ArticleLanding/2008/JM/b715826b#!divAbstract

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JF - Journal of Materials Chemistry

IS - 8

ER -

Synthesis and characterization of nanoporous phospho-tungstate organic-inorganic hybrid materials

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