Temporary mirror symmetry breaking and chiral excursions in open and closed systems

Celia Blanco, Michael Stich, David Hochberg*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review


    The reversible Frank model is capable of amplifying the initial small statistical deviations from the idealized racemic composition. This temporary amplification can be interpreted as a chiral excursion in a dynamic phase space. It is well known that if the system is open to matter and energy exchange, a permanently chiral state can be reached asymptotically, while the final state is necessarily racemic if the system is closed. In this work, we combine phase space analysis, stability analysis and numerical simulations to study the initial chiral excursions and determine how they depend on whether the system is open, semi-open or closed.

    Original languageEnglish
    Pages (from-to)140-147
    Number of pages8
    JournalChemical Physics Letters
    Issue number4-6
    Early online date16 Feb 2011
    Publication statusPublished - 30 Mar 2011

    Bibliographical note

    © 2011, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/


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